Government decree on the assessment of soil contamination and. Mtbe vapors that are extracted or vacuumed from the soil must be collected, properly treated, and disposed of to prevent further contamination. Remediation of mtbecontaminated water and soil keller. Mtbe can contaminate groundwater or soil through leaking underground or above ground storage tanks or from spills. The greatest percentage of spill sites with mtbe contamination 24% as well as the greatest number of spill sites with mtbe groundwater contamination over 50 parts per billion were found to be on long island.
The first draft of methyl tertiarybutyl ether mtbe in drinkingwater, background document for development of who guidelines for drinkingwater quality, was prepared by members of the water quality and health bureau, health canada, to whom special thanks are due. Based on historical and current data, residual soil contamination is estimated to include 323 pounds of total. The guideline values have been defined on the basis of either ecological risks e or health risks t. Mtbe soil concentrations relative to other gasoline constituents at contaminated sites article pdf available in environmental geosciences 84. Microbial community from mtbecontaminated soil for aerobic. Reported closures of mtbecontaminated water sources in california 1989. Groundwater information sheet methyl tertiarybutyl ether mtbe the purpose of this groundwater information sheet is to provide general information regarding a specific constituent of concern coc. Remediation of mtbe in soil and groundwater samples. The method showed linear calibration with a detection limit range of 4. Overview of groundwater remediation technologies for mtbe and tba. Pdf bioremediation treatment of mtbe and etbe in contaminated. Site soil and ground water analytical data evaluation volatile organic contamination including methyl tertiary butyl ether mtbe and tertiary butyl alcohol tba derived from discharges of petroleum mixtures due to biodegradability of petroleum mixturederived volatile organic contamination i. Based on these results, nysdec determined that further study of mtbe contamination of groundwater on long island was warranted.
Mtbe has been detected nationwide in soil, groundwater, and surface water. This handbook examines the remediation of mtbe in existing spills. With mtbe being distributed nationwide, the potential for contamination of soil and groundwater is substantial. Biodegradation and fate of ethyl tertbutyl ether etbe in.
Mtbe residue in environmental water and soil analysis by. Mtbe dissolves easily in water and does not stick well to soil. The work of the following working group coordinators was crucial in the. Soil remediation because it has a very high vapor pres sure and a low affinity for sorption to soil, mtbe can be effectively reme diated by two soil treatment technol ogies, typically without any costs be yond those needed for remediating other petroleum constituents. Hydrocarbon contamination of water resources is a global issue. Groundwater information sheet methyl tertiarybutyl ether mtbe.
The isolation of these bacterial strains from aerobic soil environments with contrasting contamination history implies a diverse range of microorganisms able to biodegrade etbe in isolation or simultaneously in mixtures with other geo e. When having soil or water analyzed for mtbe from contamination caused by petroleum or hazardous substances, owners and operators of ust systems must use a laboratory certified under 567chapter 83 for petroleum analyses. Mtbe primarily reaches ground water via infiltration of gasoline into water, although contamination. It has a minty smell, vaguely reminiscent of diethyl ether, leading to unpleasant taste and odor in water. Mtbe has been found in groundwater by the minnesota pollution control. Bioremediation treatment of mtbe and etbe in contaminated soils. The addition of methyl tertiarybutyl ether mtbe to gasoline. Oxygenates are added to fuel to increase its oxygen content. Treatment of methyl tertiarybutyl ether mtbecontaminated water with fentons reagent pdf 18 pp, 248k, about pdf 2003. Request pdf on jan 1, 2003, volker linnemann and others published movement of mtbe through soil after groundwater contamination find, read and cite all the research you need on researchgate. In this part of study, feasibility of mtbe bioremediation was assessed by a combined microbial culture that was separated from mtbe contaminated soil. Mtbe primarily reaches ground water via infiltration of gasoline into water, although contamination also occurs via vaporphase diffusion dakhel et al. This situation biodegradation can make treating results when benzene has attenuated and groundwater contaminated with mtbe. The high solubility and low soil adsorption of mtbe allows mtbe to be readily flushed from the aquifer.
Mtbe contamination and five examples for remediation. Groundwater information sheet methyl tertiarybutyl ether. Mtbe contamination may be an mtbe s high solubility in water, low unknown quantity that is greater than rate of adsorption to soil, and low rate of 100percent more. The iowa state survey reported 635 soil samples were contaminated with mtbe at the average contamination level of 122.
Gac treatment technique pumps contaminated water through a bed of activated carbon to remove organic compounds. Site soil and ground water analytical data evaluation. The number of water systems reporting mtbe contamination in tap water supplies increased more than 15fold between 1996 and 2004, from 7 to 1,861, and the number of states reporting problems more than doubled, from 11 to 29, according to ewg action funds. To evaluate this methods applicability, a series of experiments based on design of experiments by minitab software were done in which superficial mtbe contaminated water sam. Mtbe was found in groundwater with the concentration up to 5,000 mgl mccauluou and slater, 2002. Mtbe spreads more easily underground than other gasoline components due to its higher solubility in water. Mtbe poses special challenges because of its physicochemical properties, in particular high solubility and low henrys.
When soil is contaminated with mtbe, treatment may be even easier than for other gasoline compounds since pure mtbe has a high vapor pressure and does not sorb stick easily to organic carbon in soil. Implementation of measures to prevent further mtbe contamination. When mtbe is dissolved in water, mtbe treatment may be more difficult and time consuming than for other gasoline compounds. A method was developed for the detection of mtbe residue in environmental water and soil using an agilent 7820 gc with fid. Mtbe is a volatile, flammable, and colorless liquid that is sparingly soluble in water. Pdf mtbe soil concentrations relative to other gasoline. Mtbe, a volatile, organic chemical, is a gasoline additive that promotes more complete burning of gasoline, thereby reducing carbon monoxide and ozone levels.
For example, additional investigations required to determine the extent of mtbe impacted groundwater or the remediation of an ongoing source of mtbe soil andor groundwater contamination would be eligible. Methyl tertbutyl ether mtbe minnesota department of health. Principal greenvironment, llc montgomery, ma richard sloan president chickadee remediation co. Tbamtbeethanol remediation seminar national ground water. And herein lies the potential problem with reported mtbe results. As the number of leaking underground fuel tank sites with methyl tertiary butyl ehter mtbe contamination continues to grow, there is a need to develop costeffective solutions for treatment of soil and water contamination. Because mtbe behaves differently in soil and water than other petroleum constituents, the choice of an effective remediation technology may be different when mtbe is present with other fuel contaminants at a site. The fate of mtbe and btex in constructed wetlands mdpi. Mtbe is the common name for a synthetic chemical called methyl tertbutyl ether.
Treatment of methyl tertiarybutyl ether mtbe contaminated water with fentons reagent pdf 18 pp, 248k, about pdf 2003. Pumpandtreat has the ability to flush mtbe contaminants from the soil. The furthest downgradient portion of the plume extends into an adjacent property where mtbe had been detected as high as 1. Mtbe, bioremediation, phytoremediation introduction mtbe, more formally methyl tertbutyl ether, has been extensively used as an octane booster and oxygenate additive in reformulated gasoline in the united states. Epas federal underground storage tank ust regulations have contributed greatly to reducing soil and ground water contamination by mtbe and other fuel components from usts.
Mtbe methyltbutyl ether is a member of a group of chemicals commonly known as fuel oxygenates. Mtbe beware the false positive by blayne hartman what is the official epa method for measuring mtbe in soil and water samples. Pdf methyl tertbutyl ether mtbe bioremediation studies. The information provided herein relates to wells groundwater sources use for public drinking water, not water served at the tap. The effectiveness of remediation methods is directly linked to the physical and chemical characteristics of the constituent of concern.
The number and extent of scientific tests places mtbe within the top 2 percent of all tested substances. The mtbe remediation handbook is a comprehensive and upto date compendium of knowledge of the technology and risk management of mtbe contamination. Contaminants of concern coc at underground storage. Groundwater remediation technologies shown to be effective for the treatment and removal of mtbe and tba include both ex situ technologies pump and treat and in situ technologies air sparging, bioremediation, chemical oxidation, phytoremediation, and monitored natural attenuation. If the risk of groundwater contamination is higher than normal in concentrations below the lower guideline value, the substances are marked with the letter p. Mtbe, a fuel oxygenate, is almost exclusively used as a fuel additive. The july 2014 corrective action plan, which is entitled the mtbe remediation fund implementation plan implementation plan, calls for the preparation of an annual report by nhdes and submittal of the report to the fiscal. Mtbe dissolves in water easily and evaporates from water or soil into. In addition they must ensure all soil and water samples. Bioremediation treatment of mtbe and etbe in contaminated soils songklanakarin j. Prepared by epas office of superfund remediation and technology innovation, this report provides information on technologies used in the remediation of mtbe and other oxygenate contamination. Contaminant, media, and site typespecific remedy guidance.
Federal and state studies have found that mtbe contamination. Mtbe remediation and treatment office of underground. Cluin contaminants methyl tertiary butyl ether mtbe. The use of methyl tertiary butyl ether mtbe in gasoline sold in the u. Tier 1 guidance manual for riskbased corrective action, including computer. Impacts on human health over 200 years of industrialisation have caused soil contamination to be a widespread problem in europe. Application and performance of technologies for treatment of. Headquarters consultation for addressing methyl tertiary butyl ether mtbe contamination under the comprehensive environmental response, compensation, and liability act cercla pdf 2 pp, 32 k may 1997, oswer 9200.
Which sites are actively remediating mtbe in soil or groundwater. Pumpandtreat processes, which have been shown to have a lower effectiveness for petroleum contaminants, are effective in treating mtbe contamination due to the low affinity mtbe compound has for organics in the soil. Mtbe and etbe are very low absorbed in soil but very soluble in water. Decision makers, scientists, businesses and individual citizens generally accept and understand that air and water pollution can. Potential sources since mtbe was frequently used across indiana, it is commonly found at old gasoline station sites.
It is added to gasoline in certain areas of the country that do not meet national air quality standards including con. If the source of petroleum hydrocarbons in soil is light petroleum fractions, such as gasoline, gasohol and naphtha solvents, the soil needs to be analyzed and assessed for benzene, toluene, ethylbenzene, total xylenes, lead, methyl tertiarybutyl ether mtbe, and tph. Before the incorporation of mtbe in gasoline, the environmental management of gasoline release sites relied on the analysis of other gasoline constituents in soil and groundwater samples in order to delineate gasolineimpacted areas and assess the severity of subsurface contamination by gasoline. Apr 05, 2005 mtbe contamination is soaring although the use of mtbe in gasoline is rapidly declining, detections of mtbe in water supplies are soaring. The biological treatment of mtbe contaminated soil, water and groundwater could provide a simpler, less expensive alterna tive to chemical and physical. You asked for information about contamination of groundwater by mtbe methyl tertiary butyl ether. Mtbe drinking water contaminants, factsremoval methods. Detection of mtbe in ground and surface waters in new. Tba mtbeethanol remediation seminar national ground water association petroleum hydrocarbons and organic chemicals in ground water houston, texas november 2006 ellen moyer, ph.
Mtbe s high solubility in water, low rate of adsorption to soil, and low rate of biodegradation can make treating groundwater contaminated with mtbe more expensive than treating ground water contaminated with petroleum that does not contain mtbe. Movement of mtbe through soil after groundwater contamination. As traction wells and associated equipment a result, fewer aquifer volumes are e. Methyl tertiarybutyl ether mtbe in drinkingwater world health. Mtbe must be a significant factor in the work that is required. Guidelines for investigation and cleanup of mtbe and other ether. Insitu enhanced bioremediation of mtbe and btex at a. Mtbe contamination by state like oil and water ewg. Mtbe is used in gasoline throughout the united states to reduce carbon monoxide and ozone levels caused by auto emissions. Methyl tertbutyl ether mtbe, also known as tertbutyl methyl ether, is an organic compound with a structural formula ch 3 3 coch 3. Pdf three methyl tertiary butyl ether mtbe degradative consortia were isolated from gasolinecontaminated soil namely.
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